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The Following Toolbar Tools Are Explained In My PDF Tutorials.
Photoshop CS, CS2, CS3 and CS4/5’s Toolbar are very similar; CS3 and CS4/5 have one extra Tool, The Quick Selection Tool; this shares a fly out menu with The Magic Wand Tool.  Additionally, CS3 and CS4/5 don’t include Image Ready; animations are either created within the CS3 and CS4/5’s interface - or in a separate programme called Fireworks.
CS3, and CS4/5 have one Quick Mask (toggle) button, and the Change Screen Mode choices - Standard, Maximum, and Full Screen, share the same button - and are grouped into a drop-down list. (CS5 includes extensive built-in help files and video tutorials).

CS4/5 has two additional (3D) Tool Palettes (3D Rendering Tools).
CS4 On-line Tips, Tutorials And Adobe Support - AdobePhotoshop.com.

CS4/5’s Workspace And Palette Explained
What’s New In CS3, CS4 And CS4 Extended
A Screen Capture Of Photoshop CS, CS2, CS3, CS4, CS5 (Extended’s) Tools Toolbar Can Be viewed Here

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My tutorials are fully compatible with Adobe Photoshop CS CS2 CS3 CS4 CS5 CS6 Extended:
 many can also be adapted to work with older Photoshop versions, and Photoshop Elements.
The Main Differences Between Photoshop And Photoshop Elements!